Agradecimentos: We graciously thank K. Visbeck for assistance with DAC preparation and C. Kenney-Benson for assistance with setup at the Advanced Photon Source. This work was performed under LDRD (Tracking Code 12-ERD-013) and under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory (LLNL) under Contract No. DE-AC52-07NA27344. L. S. I. Veiga is supported by FAPESP (SP-Brazil) under Contract No. 2013/14338-3. Portions of this work were performed at Sector 4 and at HPCAT (Sector 16), Advanced Photon Source (APS), Argonne National Laboratory. HPCAT operations are supported by DOE-NNSA under Award No. DE-NA0001974 and DOE-BES under Award No. DE-FG02-99ER45775, with partial instrumentation funding by NSF. APS is supported by DOE-BES, under Contract No. DE-AC02-06CH11357. Beamtime was provided by the General User Proposal system and the Carnegie DOE-Alliance Center (CDAC). Identification of commercial materials or equipment does not imply recommendation or endorsement by the National Institute of Standards and Technology, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose Ver menos

Abstract: The compound Sm2CO17 displays magnetic properties amenable to permanent magnet applications owing to both the 3d electrons of Co and the 4f electrons of Sm. The long-standing description of the magnetic interactions between the Sm and Co ions implies a truly ferromagnetic configuration, but some recent calculations challenge this axiom, suggesting at least a propensity for ferrimagnetic behavior. We have used high-pressure synchrotron x-ray techniques to characterize the magnetic and structural properties of Sm2Co17 to reveal a robust ferromagnetic state. The local Sm moment is at most weakly affected by compression, and the ordered moments show a surprising resilience to volumetric compressions of nearly 20%. Density functional theory calculations echo the magnetic robustness of Sm2Co17 Ver menos