Agradecimentos: United States Department of Health & Human Services; National Institutes of Health (NIH) - USA; NIH National Institute of Dental & Craniofacial Research (NIDCR)

To assess the influence of hydrophilicity of reactive nanogels on the mechanical performance of dental adhesives and microtensile bond strength (mu TBS) to dentin after 24h or 3 months of aging. A series of three nanogels were synthesized: NG1 IBMA/UDMA; NG2-HEMA/BisGMA; NG3-HEMA/TE-EGDMA. The...

To assess the influence of hydrophilicity of reactive nanogels on the mechanical performance of dental adhesives and microtensile bond strength (mu TBS) to dentin after 24h or 3 months of aging. A series of three nanogels were synthesized: NG1 IBMA/UDMA; NG2-HEMA/BisGMA; NG3-HEMA/TE-EGDMA. The nanogels were dispersed in solvent, HEMA or BisGMA/HEMA. The degree of conversion (DC) of the materials was measured and the flexural modulus of these polymers was evaluated in dry or wet conditions. For mu TBS analysis, a model adhesive was used without nanogel (control) or with the incorporation of nanogels. mu TBS was evaluated after storage in distilled water for 24h or 3 months. The analysis of the fracture was performed after mu TBS testing. Data were analyzed using ANOVA and Tukey's test (alpha= 0.05). Water significantly increased the modulus of NG1 and NG2 dispersed in solvent, while significantly decreased the stiffness of NG3. All polymers dispersed in HEMA and BisGMA/HEMA had significantly lower modulus when stored in water. NG2 showed the highest DC in solvent and BisGMA/HEMA. In HEMA, NG1 and NG3 produced the highest DC. After three months, NG2 showed the best mu TBS. The mu TBS of NG2-containing adhesive resin significantly increased after 3 months, while storage had no effect in the control group, NG1 and NG3. The more hydrophobic IBMA/UDMA nanogel showed higher bulk material mechanical property results, but the best dentin bond strength values, and notably strength values that improved upon storage, were obtained with the amphiphilic nanogel based on BisGMA/HEMA

COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES

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