Liquid-liquid equilibria and density data for pseudoternary systems of refined soybean oil + (hexanal, or heptanal, or butyric acid, or valeric acid, or caproic acid, or caprylic acid) + dimethyl sulfoxide at 298.15 K
Perci O. B. Homrich, Laisa G. Dias, Lilian R. B. Mariutti, Neura Bragagnolo, Roberta Ceriani
ARTIGO
Inglês
Agradecimentos: CAPES (Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior)CAPES [33003017034P8]; FAPESP (Fundacao de Amparo a Pesquisa do Estado de Sao Paulo)Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2016/18253-0, 2014/21252-0]; FAE-PEX (Fundo de Apoio ao Ensino, a...
Ver mais
Agradecimentos: CAPES (Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior)CAPES [33003017034P8]; FAPESP (Fundacao de Amparo a Pesquisa do Estado de Sao Paulo)Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2016/18253-0, 2014/21252-0]; FAE-PEX (Fundo de Apoio ao Ensino, a Pesquisa e Extensao) [2407/16]; PROEX (Programa de Excelencia Academica) [0566/2017]; CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico)National Council for Scientific and Technological Development (CNPq) [302146/2016-4]
Ver menos
Odoriferous compounds and free fatty acids can be mildly removed from vegetable oils using organic liquid solvents. Liquid-liquid equilibrium data are presented for extraction of odoriferous compounds (hexanal, heptanal, butyric acid, valeric acid, caproic acid, and caprylic acid) from refined...
Ver mais
Odoriferous compounds and free fatty acids can be mildly removed from vegetable oils using organic liquid solvents. Liquid-liquid equilibrium data are presented for extraction of odoriferous compounds (hexanal, heptanal, butyric acid, valeric acid, caproic acid, and caprylic acid) from refined soybean oil using dimethyl sulfoxide. Six tie lines were measured for each system at 298.15 K and under atmospheric pressure. Quantification of mass fractions was carried out by gas chromatography-mass spectrometry (GC-MS) for hexanal and heptanal, by gravimetry in a vacuum oven for refined soybean oil, and by titration for carboxylic acids. Measured data showed a high extraction of short-chain carboxylic acids and very low amounts of oil in solvent-rich phases. Coefficients of partition lower than 1 were found for aldehydes. Satisfactory agreements were found for thermodynamic correlation by using the NonRandom Two-Liquids (NRTL) and the UNIversal QUAsiChemical (UNIQUAC) models, which presented global deviations lower than 0.55 and 0.71%, respectively. Moreover, four versions of the UNIFAC method were tested (UNIFAC-LL, UNIFAC-HIR, UNIFAC-DMD, and NIST-UNIFAC), wherein reasonable agreements were found for few cases
Ver menos
CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ
302146/2016-4
COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES
33003017034P8
FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP
2016/18253-0; 2014/21252-0
Fechado
Liquid-liquid equilibria and density data for pseudoternary systems of refined soybean oil + (hexanal, or heptanal, or butyric acid, or valeric acid, or caproic acid, or caprylic acid) + dimethyl sulfoxide at 298.15 K
Perci O. B. Homrich, Laisa G. Dias, Lilian R. B. Mariutti, Neura Bragagnolo, Roberta Ceriani
Liquid-liquid equilibria and density data for pseudoternary systems of refined soybean oil + (hexanal, or heptanal, or butyric acid, or valeric acid, or caproic acid, or caprylic acid) + dimethyl sulfoxide at 298.15 K
Perci O. B. Homrich, Laisa G. Dias, Lilian R. B. Mariutti, Neura Bragagnolo, Roberta Ceriani
Fontes
|
The Journal of Chemical Thermodynamics Vol. 131 (Apr., 2019), p. 149-158 |