Use of gas diffusion electrode for the in situ generation of hydrogen peroxide in an electrochemical flow-by reactor
Rafael M. Reis, Andr e A. G. F. Beati, Robson S. Rocha, Mônica H. M. T. Assumpção, Mauro C. Santos, Rodnei Bertazzoli, Marcos R. V. Lanza
ARTIGO
Inglês
Agradecimentos: The authors gratefully acknowledge the following Brazilian Funding Institutions for financial support: Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), and Conselho Nacional de Desenvolvimento...
Agradecimentos: The authors gratefully acknowledge the following Brazilian Funding Institutions for financial support: Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), and Conselho Nacional de Desenvolvimento Cientifico e Tecnológico CNPq)
Hydrogen peroxide is a powerful oxidant that finds application in several areas, but most particularly in the treatment of industrial wastewaters. The aim of the present study was to investigate the effects of applied potential and electrolyte flow conditions on the in situ generation of hydrogen...
Hydrogen peroxide is a powerful oxidant that finds application in several areas, but most particularly in the treatment of industrial wastewaters. The aim of the present study was to investigate the effects of applied potential and electrolyte flow conditions on the in situ generation of hydrogen peroxide in an electrochemical flow-by reactor with a gas diffusion electrode (GDE). The electrolyses were performed in an aqueous acidic medium using a GDE constructed with conductive black graphite and polytetrafluoroethylene (80:20 w/w). Under laminar flow conditions (flow rate = 50 L/h), hydrogen peroxide was formed in a maximum yield of 414 mg/L after 2 h at 2.25 V vs Pt //Ag/AgCl (global rate constant = 3.1 mg/(L min); energy consumption = 22.1 kWh/kg). Under turbulent flow (300 L/h), the maximum yield obtained was 294 mg/L after 2 h at 1.75 V vs Pt//Ag/AgCl (global rate constant = 2.5 mg/(L min); energy consumption = 30.1 kWh/kg)
FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP
CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ
COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES
Fechado
DOI: https://doi.org/10.1021/ie201317u
Texto completo: https://pubs.acs.org/doi/10.1021/ie201317u
Use of gas diffusion electrode for the in situ generation of hydrogen peroxide in an electrochemical flow-by reactor
Rafael M. Reis, Andr e A. G. F. Beati, Robson S. Rocha, Mônica H. M. T. Assumpção, Mauro C. Santos, Rodnei Bertazzoli, Marcos R. V. Lanza
Use of gas diffusion electrode for the in situ generation of hydrogen peroxide in an electrochemical flow-by reactor
Rafael M. Reis, Andr e A. G. F. Beati, Robson S. Rocha, Mônica H. M. T. Assumpção, Mauro C. Santos, Rodnei Bertazzoli, Marcos R. V. Lanza
Fontes
Industrial and engineering chemistry research Vol. 51, no. 2 (Jan., 2012), p. 649-654 |