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dc.contributor.CRUESPUNIVERSIDADE DE ESTADUAL DE CAMPINASpt_BR
dc.typeArtigo de periódicopt_BR
dc.titleAmbient Sonic-spray Ionization Mass Spectrometry For Rapid Monitoring Of Secondary Oxidation Products In Biodieselpt_BR
dc.contributor.authorPereira G.G.pt_BR
dc.contributor.authorAlberici R.M.pt_BR
dc.contributor.authorFernandes G.D.pt_BR
dc.contributor.authorCunha I.B.S.pt_BR
dc.contributor.authorEberlin M.N.pt_BR
dc.contributor.authorDobarganes M.C.pt_BR
dc.contributor.authorDaroda R.J.pt_BR
dc.contributor.authorBarrera-Arellano D.pt_BR
unicamp.authorPereira, G.G., Fats and Oils Laboratory, Faculty of Food Engineering, University of Campinas - UNICAMP, Campinas, SP, Brazilpt_BR
unicamp.authorAlberici, R.M., ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, University of Campinas - UNICAMP, Campinas, SP, Brazil, National Institute of Metrology, Quality and Technology (INMETRO), Duque de Caxias, RJ, Brazilpt_BR
unicamp.authorFernandes, G.D., Fats and Oils Laboratory, Faculty of Food Engineering, University of Campinas - UNICAMP, Campinas, SP, Brazilpt_BR
unicamp.authorCunha, I.B.S., ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, University of Campinas - UNICAMP, Campinas, SP, Brazilpt_BR
unicamp.authorEberlin, M.N., ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, University of Campinas - UNICAMP, Campinas, SP, Brazilpt_BR
unicamp.authorBarrera-Arellano, D., Fats and Oils Laboratory, Faculty of Food Engineering, University of Campinas - UNICAMP, Campinas, SP, Brazilpt_BR
unicamp.author.externalDobarganes, M.C., Instituto de la Grasa (CSIC), Avda Padre Garcia Tejero, Spainpt
unicamp.author.externalDaroda, R.J., National Institute of Metrology, Quality and Technology (INMETRO), Duque de Caxias, RJ, Brazilpt
dc.description.abstractThis paper proposes the use of easy ambient sonic-spray ionization mass spectrometry (EASI-MS) to detect markers of high-level oxidation in biodiesel via a simple and rapid single-shot analytical protocol. Soybean biodiesel was oxidized in Rancimat and then analyzed at different time periods by both EASI-MS and traditional physicochemical methods. Major changes in the EASI(+)-MS profile as well in the peroxide value, acidity, and kinematic viscosity were observed after the induction period (IP). Fatty acid methyl esters (FAME) and their respective hydroperoxides were primarily identified using EASI-MS in fresh biodiesel and at the initial stages of oxidation. After the IP, EASI-MS revealed the formation of dimers and low-mass non-volatile molecules, such as aldehydes, due to hydroperoxide breakdown. Both the dimers and aldehydes are attributed to secondary oxidation products. Therefore, EASI-MS was found to provide a fast, direct, and accurate technique to identify markers in biodiesel with high-level of oxidation. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.relation.ispartofEuropean Journal of Lipid Science and Technologypt_BR
dc.publisherWiley-VCH Verlagpt_BR
dc.date.issued2014pt_BR
dc.identifier.citationEuropean Journal Of Lipid Science And Technology. Wiley-vch Verlag, v. 116, n. 8, p. 952 - 960, 2014.pt_BR
dc.language.isoenpt_BR
dc.description.volume116pt_BR
dc.description.issuenumber8pt_BR
dc.description.firstpage952pt_BR
dc.description.lastpage960pt_BR
dc.rightsfechadopt_BR
dc.sourceScopuspt_BR
dc.identifier.issn14387697pt_BR
dc.identifier.doi10.1002/ejlt.201300482pt_BR
dc.identifier.urlhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84905485677&partnerID=40&md5=f71f17758e69d15118230a2fb38a05e7pt_BR
dc.date.available2015-06-25T17:52:10Z
dc.date.available2015-11-26T14:14:15Z-
dc.date.accessioned2015-06-25T17:52:10Z
dc.date.accessioned2015-11-26T14:14:15Z-
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dc.description.provenanceMade available in DSpace on 2015-11-26T14:14:15Z (GMT). No. of bitstreams: 2 2-s2.0-84905485677.pdf: 508107 bytes, checksum: 3476a37e3d13fa542f9a621727eb7b10 (MD5) 2-s2.0-84905485677.pdf.txt: 31733 bytes, checksum: 98e9626dfb954eb369524fd50ac569dd (MD5) Previous issue date: 2014en
dc.identifier.urihttp://www.repositorio.unicamp.br/handle/REPOSIP/86228
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/86228-
dc.identifier.idScopus2-s2.0-84905485677pt_BR
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