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dc.contributor.CRUESPUNIVERSIDADE DE ESTADUAL DE CAMPINASpt_BR
dc.typeArtigo de periódicopt_BR
dc.titleDesorption/ionization Efficiencies Of Triacylglycerols And Phospholipids Via Easi-mspt_BR
dc.contributor.authorFernandes A.M.A.P.pt_BR
dc.contributor.authorFernandes G.D.pt_BR
dc.contributor.authorBarrera-Arellano D.pt_BR
dc.contributor.authorDe Sa G.F.pt_BR
dc.contributor.authorLins R.D.pt_BR
dc.contributor.authorEberlin M.N.pt_BR
dc.contributor.authorAlberici R.M.pt_BR
unicamp.authorFernandes, A.M.A.P., ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, University of Campinas - UNICAMP, Campinas SP 13083-970, Brazilpt_BR
unicamp.authorFernandes, G.D., Fats and Oils Laboratory, Faculty of Food Engineering, University of Campinas - UNICAMP, Campinas 13083-970 SP, Brazilpt_BR
unicamp.authorBarrera-Arellano, D., Fats and Oils Laboratory, Faculty of Food Engineering, University of Campinas - UNICAMP, Campinas 13083-970 SP, Brazilpt_BR
unicamp.authorEberlin, M.N., ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, University of Campinas - UNICAMP, Campinas SP 13083-970, Brazilpt_BR
unicamp.authorAlberici, R.M., ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, University of Campinas - UNICAMP, Campinas SP 13083-970, Brazilpt_BR
unicamp.author.externalDe Sá, G.F., Department of Fundamental Chemistry, Federal University of Pernambuco, Recife 50740-560 PE, Brazilpt
unicamp.author.externalLins, R.D., Department of Fundamental Chemistry, Federal University of Pernambuco, Recife 50740-560 PE, Brazilpt
dc.description.abstractKnowledge of the major effects governing desorption/ionization efficiency is required for the development and application of ambient mass spectrometry. Although all triacylglycerols (TAG) have the same favorable protonation and cationization sites, their desorption/ionization efficiencies can vary dramatically during easy ambient sonic-spray ionization because of structural differences in the carbon chain. To quantify this somewhat surprising and drastic effect, we have performed a systematic investigation of desorption/ionization efficiencies as a function of unsaturation and length for TAG as well as for diacylglycerols, monoacylglycerols and several phospholipids (PL). Affinities for Na+ as a function of unsaturation level have also been assayed via comprehensive metadynamics calculations to understand the influence of this phenomenon on the ionization efficiency. The results suggest that dipole-dipole interactions within a carbon chain tuned by unsaturation sites govern ionization efficiency of TAG and PL. Copyright © 2014 John Wiley & Sons, Ltd.en
dc.relation.ispartofJournal of Mass Spectrometrypt_BR
dc.publisherJohn Wiley and Sons Ltdpt_BR
dc.date.issued2014pt_BR
dc.identifier.citationJournal Of Mass Spectrometry. John Wiley And Sons Ltd, v. 49, n. 5, p. 335 - 341, 2014.pt_BR
dc.language.isoenpt_BR
dc.description.volume49pt_BR
dc.description.issuenumber5pt_BR
dc.description.firstpage335pt_BR
dc.description.lastpage341pt_BR
dc.rightsfechadopt_BR
dc.sourceScopuspt_BR
dc.identifier.issn10765174pt_BR
dc.identifier.doi10.1002/jms.3366pt_BR
dc.identifier.urlhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84900037361&partnerID=40&md5=0785996435c26fad5482422d1e00c2fapt_BR
dc.date.available2015-06-25T17:51:05Z
dc.date.available2015-11-26T15:39:58Z-
dc.date.accessioned2015-06-25T17:51:05Z
dc.date.accessioned2015-11-26T15:39:58Z-
dc.description.provenanceMade available in DSpace on 2015-06-25T17:51:05Z (GMT). No. of bitstreams: 0 Previous issue date: 2014en
dc.description.provenanceMade available in DSpace on 2015-11-26T15:39:58Z (GMT). No. of bitstreams: 0 Previous issue date: 2014en
dc.identifier.urihttp://www.repositorio.unicamp.br/handle/REPOSIP/85979
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/85979-
dc.identifier.idScopus2-s2.0-84900037361pt_BR
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