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|Type:||Artigo de periódico|
|Title:||Photocatalytic Degradation Of Ofloxacin And Evaluation Of The Residual Antimicrobial Activity|
|Abstract:||Ofloxacin is an antimicrobial agent frequently found in significant concentrations in wastewater and surface water. Its continuous introduction into the environment is a potential risk to non-target organisms or to human health. In this study, ofloxacin degradation by UV/TiO2 and UV/TiO2/H2O2, antimicrobial activity (E. coli) of samples subjected to these processes, and by-products formed were evaluated. For UV/TiO2, the degradation efficiency was 89.3% in 60 min of reaction when 128 mg L-1 TiO2 were used. The addition of 1.68 mmol L-1 hydrogen peroxide increased degradation to 97.8%. For UV/TiO2, increasing the catalyst concentration from 4 to 128 mg L-1 led to an increase in degradation efficiency. For both processes, the antimicrobial activity was considerably reduced throughout the reaction time. The structures of two by-products are presented: m/z 291 (9-fluoro-3-methyl-10-(methyleneamino)-7-oxo-2,3-dihydro-7H-[1,4]oxazino[2,3,4-ij]quinoline-6-carboxylic acid) and m/z 157 ((Z)-2-formyl-3-((2-oxoethyl)imino)propanoic acid).|
|Editor:||Royal Society of Chemistry|
|Citation:||Photochemical And Photobiological Sciences. Royal Society Of Chemistry, v. 14, n. 3, p. 556 - 562, 2015.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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