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Type: Artigo de periódico
Title: Adsorption and preconcentration of 2,4-dichlorophenoxyacetic acid on a chemically modified silica gel surface
Author: Prado, AGS
Airoldi, C
Abstract: The herbicide 2,4-dichlorophenoxyacetic acid (2,4-D), chemically anchored to a silica gel surface, was used to adsorb and preconcentrate the same herbicide from aqueous solutions at room temperature. From a series of adsorption isotherms adjusted to a modified Langmuir equation, the maximum number of moles adsorbed was calculated as 4.67x10(-5) mol g(-1), with the highest retention capacity at pH 5. This modified silica gel was used in a column for preconcentrating trace levels of 2,4-D. The preconcentrated herbicide can be directly eluted with methanol with a recovery efficiency higher than 97%. The concentration factor was 8.33.
Country: EUA
Editor: Springer-verlag
Citation: Fresenius Journal Of Analytical Chemistry. Springer-verlag, v. 371, n. 7, n. 1028, n. 1030, 2001.
Rights: fechado
Identifier DOI: 10.1007/s00216-001-1097-6
Date Issue: 2001
Appears in Collections:Unicamp - Artigos e Outros Documentos

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