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dc.contributor.CRUESPUniversidade Estadual de Campinaspt_BR
dc.typeArtigo de periódicopt_BR
dc.titleTHE MIRAGE EFFECT - A SENSITIVE PROBE FOR ELECTROCHEMICAL-CELL CALORIMETRYpt_BR
dc.contributor.authorROSOLEN, JMpt_BR
dc.contributor.authorFRACASTORODECKER, Mpt_BR
dc.contributor.authorDECKER, Fpt_BR
unicamp.authorUNICAMP,INST FIS,CAMPINAS,SP,BRAZILpt_BR
dc.subject.wosPhotothermal Deflection Spectroscopypt_BR
dc.subject.wosBeam Deflectionpt_BR
dc.subject.wosFilmspt_BR
dc.description.abstractMeasurements of the mirage deflection in an electrochemical cell, where Cu electrodeposition and the ferro/ferricyanate reaction occurred, were performed in the dark under a potential step and in ac conditions with the aim of detecting thermal phenomena due to Joule and Peltier effects at the interface. A mathematical model based on the diffusion of thermal and ionic waves into the electrolyte allowed simulation of the mirage deflection in all cases. The experimental conditions under which the model is valid and the thermal effects can be separated from the ionic effects were discussed. Finally, the Peltier coefficient of the ferro/ferricyanate redox couple could also be measured using the ac technique.pt
dc.relation.ispartofJournal Of Electroanalytical Chemistrypt_BR
dc.relation.ispartofabbreviationJ. Electroanal. Chem.pt_BR
dc.publisher.cityLausanne 1pt_BR
dc.publisher.countrySuíçapt_BR
dc.publisherElsevier Science Sa Lausannept_BR
dc.date.issued1993pt_BR
dc.date.monthofcirculation40238pt_BR
dc.identifier.citationJournal Of Electroanalytical Chemistry. Elsevier Science Sa Lausanne, v. 346, n. 41671, n. 119, n. 133, 1993.pt_BR
dc.language.isoenpt_BR
dc.description.volume346pt_BR
dc.description.issuenumber41671pt_BR
dc.description.firstpage119pt_BR
dc.description.lastpage133pt_BR
dc.rightsfechadopt_BR
dc.rights.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policypt_BR
dc.sourceWeb of Sciencept_BR
dc.identifier.issn0022-0728pt_BR
dc.identifier.wosidWOS:A1993KQ71000007pt_BR
dc.identifier.doi10.1016/0022-0728(93)85007-4pt_BR
dc.date.available2014-12-16T11:35:16Z
dc.date.available2015-11-26T17:07:23Z-
dc.date.accessioned2014-12-16T11:35:16Z
dc.date.accessioned2015-11-26T17:07:23Z-
dc.description.provenanceMade available in DSpace on 2014-12-16T11:35:16Z (GMT). No. of bitstreams: 1 WOSA1993KQ71000007.pdf: 896036 bytes, checksum: 11e802b0b06b2a47232eb75b01f30789 (MD5) Previous issue date: 1993en
dc.description.provenanceMade available in DSpace on 2015-11-26T17:07:23Z (GMT). No. of bitstreams: 2 WOSA1993KQ71000007.pdf: 896036 bytes, checksum: 11e802b0b06b2a47232eb75b01f30789 (MD5) WOSA1993KQ71000007.pdf.txt: 31180 bytes, checksum: 65fcd34c6877f8d070fbed6587609c37 (MD5) Previous issue date: 1993en
dc.identifier.urihttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/73640pt_BR
dc.identifier.urihttp://www.repositorio.unicamp.br/handle/REPOSIP/73640
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/73640-
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