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|Type:||Artigo de periódico|
|Title:||Gauche Preference of beta-Fluoroalkyl Ammonium Salts|
|Abstract:||The strong gauche preference along with the F-C-C-N+ fragment in 3-fluoropiperidinium cation and analogues, in the gas phase, is dictated by electrostatic interactions, which can be both hydrogen bond F center dot center dot center dot H(N+) and F/N+ attraction. In aqueous solution, where most biochemical processes take place, electrostatic effects are strongly attenuated and hyperconjugation is calculated to be at least competitive with Lewis-type interactions.|
|Editor:||Amer Chemical Soc|
|Citation:||Journal Of Physical Chemistry A. Amer Chemical Soc, v. 118, n. 2, n. 503, n. 507, 2014.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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