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dc.contributor.CRUESPUniversidade Estadual de Campinaspt_BR
dc.typeArtigo de periódicopt_BR
dc.titleFibrous cerium(IV) acid phosphates host of weak and strong Lewis basespt_BR
dc.contributor.authorRomano, Rpt_BR
dc.contributor.authorAlves, OLpt_BR
unicamp.author.emailrromano@iqm.unicamp.brpt_BR
unicamp.authorUNICAMP, Inst Quim, Lab Quim Estado Solido, BR-13084971 Campinas, SP, Brazilpt_BR
dc.subjectCePpt_BR
dc.subjectfibrouspt_BR
dc.subjectinsertionpt_BR
dc.subjectintercalationpt_BR
dc.subjectlayered acid phosphatespt_BR
dc.subjecttetravalent metal phosphatespt_BR
dc.subject.wosCrystalline Insoluble Saltspt_BR
dc.subject.wosNylon-6-clay Hybridpt_BR
dc.subject.wosPolybasic Metalspt_BR
dc.subject.wosClay Hybridpt_BR
dc.subject.wosHydrogenphosphatept_BR
dc.subject.wosSpectrapt_BR
dc.subject.wosImmobilizationpt_BR
dc.subject.wosExchangerspt_BR
dc.subject.wosSorptionpt_BR
dc.description.abstractIn this paper, we evaluated the behavior of fibrous cerium (IV) acid phosphate (CeP) in insertion procedures involving a strong Lewis base (ethylamine) and a weak one (e-caprolactam). In the former case, the procedure was performed by exposing a sample of CeP to a saturated amine atmosphere. Insertion was shown to be independent of the crystallinity of CeP, and the products showed strong host-guest interactions of the Coulombic type. Conversely, epsilon-caprolactam insertion was achieved by immersing CeP samples into its fused form. This process was dependent on the crystallinity of the inorganic solid, and host-guest interactions were characterized as involving hydrogen bonds.pt
dc.relation.ispartofJournal Of Inclusion Phenomena And Macrocyclic Chemistrypt_BR
dc.relation.ispartofabbreviationJ. Incl. Phenom. Macrocycl. Chem.pt_BR
dc.publisher.cityDordrechtpt_BR
dc.publisher.countryHolandapt_BR
dc.publisherSpringerpt_BR
dc.date.issued2005pt_BR
dc.date.monthofcirculationAPRpt_BR
dc.identifier.citationJournal Of Inclusion Phenomena And Macrocyclic Chemistry. Springer, v. 51, n. 41732, n. 211, n. 217, 2005.pt_BR
dc.language.isoenpt_BR
dc.description.volume51pt_BR
dc.description.issuenumber41732pt_BR
dc.description.firstpage211pt_BR
dc.description.lastpage217pt_BR
dc.rightsfechadopt_BR
dc.rights.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0pt_BR
dc.sourceWeb of Sciencept_BR
dc.identifier.issn0923-0750pt_BR
dc.identifier.wosidWOS:000230594600012pt_BR
dc.identifier.doi10.1007/s10847-004-7732-zpt_BR
dc.date.available2014-11-19T13:04:37Z
dc.date.available2015-11-26T18:03:19Z-
dc.date.accessioned2014-11-19T13:04:37Z
dc.date.accessioned2015-11-26T18:03:19Z-
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dc.description.provenanceMade available in DSpace on 2015-11-26T18:03:19Z (GMT). No. of bitstreams: 2 WOS000230594600012.pdf: 502063 bytes, checksum: c4aca2221715df04061bb3c43637145a (MD5) WOS000230594600012.pdf.txt: 26985 bytes, checksum: cdd95248ae05f73084bdacfaf76a311c (MD5) Previous issue date: 2005en
dc.identifier.urihttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/66918pt_BR
dc.identifier.urihttp://www.repositorio.unicamp.br/handle/REPOSIP/66918
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/66918-
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