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Type: Artigo de periódico
Title: Iron Complex with Ionic Tag-Catalyzed Olefin Reduction under Oxidative Conditions-A Different Reaction for Iron
Author: dos Santos, MR
Gomes, AF
Gozzo, FC
Suarez, PAZ
Neto, BAD
Abstract: An iron(III) complex with ionic tags was applied to the reduction of alkenes in imidazolium-based ionic liquids (ILs) under oxidative conditions. The catalyst is very efficient to promote reactions of biomass derivatives. At least ten recycling reactions were performed without any loss of catalytic activity. Some important mechanistic insights for this new reaction are also provided based mostly on electrospray ionization quadrupole-time of flight mass spectrometry (ESI-QTOF-MS).
Subject: ionic liquids
isotopic labeling
mass spectrometry
Country: Alemanha
Editor: Wiley-v C H Verlag Gmbh
Citation: Chemsuschem. Wiley-v C H Verlag Gmbh, v. 5, n. 12, n. 2383, n. 2389, 2012.
Rights: fechado
Identifier DOI: 10.1002/cssc.201200344
Date Issue: 2012
Appears in Collections:Unicamp - Artigos e Outros Documentos

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