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Type: Artigo de periódico
Title: Indigo Carmine degradation by hypochlorite in aqueous medium monitored by electrospray ionization mass spectrometry
Author: de Urzedo, APFM
Nascentes, CC
Diniz, MER
Catharino, RR
Eberlin, MN
Augusti, R
Abstract: The degradation of the dye Indigo Carmine by hypochlorite in aqueous solution was monitored by electrospray ionization mass spectrometry in the negative ion mode (ESI(-)-MS). Hypochlorite was highly efficient in removing the color of aqueous solutions of the dye. ESI(-)-MS monitoring showed that concomitant with the Indigo Carmine consumption two transient species appeared (detected as doubly charged anions) probably formed via a net insertion of two hydroxyl groups at the exocyclic C=C bond followed by the incorporation of two (mainly) or one oxygen atoms at the indolic rings of the dye. Structures of these products were proposed based on the ESI(-)-MS/MS data and high accuracy mass measurements. These two transient intermediates quickly decomposed, both in the condensed and in the gas phase, to yield mono-charged anions. Based on these results, a route for the Indigo Carmine degradation by hypochlorite in aqueous solution has been proposed. Copyright (C) 2007 John Wiley & Sons, Ltd.
Country: Inglaterra
Editor: John Wiley & Sons Ltd
Citation: Rapid Communications In Mass Spectrometry. John Wiley & Sons Ltd, v. 21, n. 12, n. 1893, n. 1899, 2007.
Rights: fechado
Identifier DOI: 10.1002/rcm.3037
Date Issue: 2007
Appears in Collections:Unicamp - Artigos e Outros Documentos

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