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Type: Artigo de periódico
Title: Application of Brazilian kaolinite clay as adsorbent to removal of U(VI) from aqueous solution: Kinetic and thermodynamic of cation-basic interactions
Author: Guerra, DL
Leidens, VL
Viana, RR
Airoldi, C
Abstract: The compound N(1)[3-(trimethoxysilyl)propyl]diethylenetriamine was anchored onto Amazon kaolinite surface by heterogeneous route. The modified and natural kaolinite samples were characterized by transmission electron microscopy, scanning electron microscopic. X-ray diffraction, and nuclear magnetic nuclei of (29)Si and (13)C. The well-defined peaks obtained in the (13)C NMR spectrum in the 5.0-62.1 ppm region confirmed the attachment of organic functional groups as pendant chains bonded into the porous clay. The ability of these materials to remove U(VI) from aqueous solution was followed by a series of adsorption isotherms adjusted to a Sips equation at room temperature and pH 4.0. The kinetic parameters analyzed by the Lagergren and Elovich models gave a good fit for a pseudo-second order reaction with k(2) values 16.0 and 25.1 mmol g(-1) min(-1) ranges for natural and modified kaolinite clays, respectively. The energetic effects caused by metal ion adsorption were determined through calorimetric titrations. (C) 2010 Published by Elsevier Inc.
Subject: Kaolinite
Country: EUA
Editor: Academic Press Inc Elsevier Science
Citation: Journal Of Solid State Chemistry. Academic Press Inc Elsevier Science, v. 183, n. 5, n. 1141, n. 1149, 2010.
Rights: fechado
Identifier DOI: 10.1016/j.jssc.2010.03.021
Date Issue: 2010
Appears in Collections:Unicamp - Artigos e Outros Documentos

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