Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/348953
Type: Artigo
Title: Resolution of isomeric multi‐ruthenated porphyrins by travelling wave ion mobility mass spectrometry
Author: Lalli, Priscila M.
Iglesias, Bernardo A.
Deda, Daiana K.
Toma, Henrique E.
Sa, Gilberto F. de
Daroda, Romeu J.
Araki, Koiti
Eberlin, Marcos N.
Abstract: The ability of travelling wave ion mobility mass spectrometry (TWIM‐MS) to resolve cationic meta/para and cis/trans isomers of mono‐, di‐, tri‐ and tetra‐ruthenated supramolecular porphyrins was investigated. All meta isomers were found to be more compact than the para isomers and therefore mixtures of all isomeric pairs could be properly resolved with baseline or close to baseline peak‐to‐peak resolution (Rp‐p). Di‐substituted cis/trans isomers were found, however, to present very similar drift times and could not be resolved. N2 and CO2 were tested as the drift gas, and similar α but considerably better values of Rp and Rp‐p were always observed for CO2
Subject: Porfirinas
Mobilidade iônica
Country: Reino Unido
Editor: John Wiley & Sons
Rights: Fechado
Identifier DOI: 10.1002/rcm.5314
Address: https://onlinelibrary.wiley.com/doi/full/10.1002/rcm.5314
Date Issue: 2012
Appears in Collections:IQ - Artigos e Outros Documentos

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