Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/335055
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dc.contributor.CRUESPUNIVERSIDADE ESTADUAL DE CAMPINASpt_BR
dc.contributor.authorunicampSantos, Matheus Fernandes dospt_BR
dc.contributor.authorunicampKatic, Verapt_BR
dc.contributor.authorunicampSantos, Pãmyla Layene dospt_BR
dc.contributor.authorunicampPires, Bruno Morandipt_BR
dc.contributor.authorunicampFormiga, André Luiz Barbozapt_BR
dc.contributor.authorunicampBonacin, Juliano Alvespt_BR
dc.typeArtigopt_BR
dc.title3D-printed low-cost spectroelectrochemical cell for in situ Raman measurementspt_BR
dc.contributor.authorSantos, Matheus F. dospt_BR
dc.contributor.authorKatic, Verapt_BR
dc.contributor.authorSantos, Pãmyla L. dospt_BR
dc.contributor.authorPires, Bruno M.pt_BR
dc.contributor.authorFormiga, André L. B.pt_BR
dc.contributor.authorBonacin, Juliano A.pt_BR
dc.subjectEspectroeletroquimicapt_BR
dc.subjectImpressão tridimensionalpt_BR
dc.subjectEspectroscopia Ramanpt_BR
dc.subjectCusto beneficiopt_BR
dc.subject.otherlanguageSpectroelectrochemistry; Raman spectroscopy; Three-dimensional printing; Cost-benefitpt_BR
dc.description.abstractRaman spectroelectrochemistry is a powerful technique for characterizing structural changes of materials during electrochemical reactions and investigating the mechanism of film deposition and adsorption processes on the surfaces of electrodes. Moreover, in situ measurements enable identification of catalytic sites and reaction intermediates, which facilitates the comprehension of reaction mechanisms. The limitations of this technique include the high-cost and the complexity of the experimental arrangement required by commercial spectroelectrochemical cells (SEC). Thus, 3D-printing technology emerges as an excellent alternative for the production of SEC, with desirable shape, low-cost, and robustness in a short period of time. In this work, an SEC and a 3D-printed working electrode were fabricated from acrylonitrile–butadiene–styrene (ABS) and conductive graphene polylactic acid (PLA) filaments, respectively. The proposed SEC and the 3D-printed electrode were printed within 3.5 h with an estimated cost of materials of less than US $2. Then, the 3D-printed SEC and the electrode were used in a study of structural changes of Prussian blue according to different voltage biaspt
dc.relation.ispartofAnalytical chemistrypt_BR
dc.relation.ispartofabbreviationAnal. chem.pt_BR
dc.publisher.cityWashington, DCpt_BR
dc.publisher.countryEstados Unidospt_BR
dc.publisherAmerican Chemical Societypt_BR
dc.date.issued2019pt_BR
dc.date.monthofcirculationJulypt_BR
dc.language.isoengpt_BR
dc.description.volume91pt_BR
dc.description.issuenumber16pt_BR
dc.description.firstpage10386pt_BR
dc.description.lastpage10389pt_BR
dc.rightsfechadopt_BR
dc.identifier.issn0003-2700pt_BR
dc.identifier.eissn1520-6882pt_BR
dc.identifier.doi10.1021/acs.analchem.9b01518pt_BR
dc.identifier.urlhttps://pubs.acs.org/doi/full/10.1021/acs.analchem.9b01518pt_BR
dc.description.sponsorshipCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL E NÍVEL SUPERIORpt_BR
dc.description.sponsorshipCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOpt_BR
dc.description.sponsorshipFAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOpt_BR
dc.description.sponsorshipINCT - INSTITUTO NACIONAL DE CIÊNCIA, TECNOLOGIA E INOVAÇÃO EM MATERIAIS COMPLEXOS FUNCIONAISpt_BR
dc.description.sponsorship1459923/2014-5pt_BR
dc.description.sponsorship12013/22127-2; 2017/23960-0pt_BR
dc.date.available2019-09-23T17:07:20Z-
dc.date.accessioned2019-09-23T17:07:20Z-
dc.description.provenanceMade available in DSpace on 2019-09-23T17:07:20Z (GMT). No. of bitstreams: 0 Previous issue date: 2019en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/335055-
dc.contributor.departmentInformação não encontradapt_BR
dc.contributor.departmentInformação não encontradapt_BR
dc.contributor.departmentInformação não encontradapt_BR
dc.contributor.departmentInformação não encontradapt_BR
dc.contributor.departmentQuímica Inorgânicapt_BR
dc.contributor.departmentQuímica Inorgânicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.subject.keyword3D printing; Spectroelectrochemical cellpt_BR
dc.creator.orcid0000-0002-8105-1090pt_BR
dc.creator.orcid0000-0003-0188-8892pt_BR
dc.creator.orcidinformação não encontradapt_BR
dc.creator.orcid0000-0001-7208-1119pt_BR
dc.creator.orcid0000-0001-6773-8083pt_BR
dc.creator.orcid0000-0001-9399-1031pt_BR
dc.type.formArtigopt_BR
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