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Type: Artigo de periódico
Title: Total Synthesis Of (-)-basiliskamide B
Author: Dias L.C.
Goncalves C.D.C.S.
Abstract: The total synthesis of the polyketide antibiotic (-)-basiliskamide B is described. The convergent asymmetric synthesis relies on the use of a diastereoselective ethyl ketone aldol reaction followed by a syn selective reduction of a β-hydroxy ketone and a Stille cross-coupling between a Z-vinylstannane and an E-vinyl iodide to establish the (Z,E)-dienamide moiety. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
Citation: Advanced Synthesis And Catalysis. , v. 350, n. 7-8, p. 1017 - 1021, 2008.
Rights: fechado
Identifier DOI: 10.1002/adsc.200700589
Date Issue: 2008
Appears in Collections:Unicamp - Artigos e Outros Documentos

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